I'm trying to have all the CV's that are in the form profile referenced in the WF Profile open in Spreadsheet when I'm in the windows app.

I think you will have to create the excel file and upload it to your second screenshot in the general section.
You initially need to build an excel template with a live cube view connection. Save that template in the fileshare (by save, I do not mean save an offline copy, just a normal save), then attach the excel file to the spreadsheet form template. When the user accesses the spreadsheet form in OS, the form will open a live cube view in spreadsheet.